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Here's Sienna Miller smoking a cigarette whilst bundled up in a black fur coat for the winter. She got this smoke in during an intermission of Hugh Dancy's New York play.
Pacific Coast News
In this photo (2006), Sienna Miller is smoking a cigarette during a script reading for the movie "Camille." The first photo was taken in 2010, so it looks like Sienna Miller is a long time smoker (or at least 4 years).